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If you can obtain the IP address of the person, then yes, you will be able to know what country, general location, ISP, etc about the person. I've not used Google Talk enough to be know, but sometimes finding an IP from an IM type program can be a bit challenging.
IP2LOCATION is a website where you can verify an IP address and get that information. It will not tell you who the person is however. But, if you can get the IP it may be enough to tell you if it's the person you believed it to be.
The easiest way to obtain the IP address is from the routing information on an email. But, if this is someone you don't wish to have on your Google Talk list, it's also likely someone you don't want to have your email address too.
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